526 research outputs found
Whispering Gallery Mode Resonator Stabilized Narrow Linewidth Fiber Loop Laser
We demonstrate a narrow line, fiber loop laser using Erbium-doped fiber as
the gain material, stabilized by using a microsphere as a transmissive
frequency selective element. Stable lasing with a linewidth of 170 kHz is
observed, limited by the experimental spectral resolution. A linear increase in
output power and a red-shift of the lasing mode were also observed with
increasing pump power. Its potential application is also discussed
Optomechanical position detection enhanced by de-amplification using intracavity squeezing
It has been predicted and experimentally demonstrated that by injecting
squeezed light into an optomechanical device it is possible to enhance the
precision of a position measurement. Here, we present a fundamentally different
approach where the squeezing is created directly inside the cavity by a
nonlinear medium. Counterintuitively, the enhancement of the signal to noise
ratio works by de-amplifying precisely the quadrature that is sensitive to the
mechanical motion without losing quantum information. This enhancement works
for systems with a weak optomechanical coupling and/or strong mechanical
damping. This could allow for larger mechanical bandwidth of quantum limited
detectors based on optomechanical devices. Our approach can be
straightforwardly extended to Quantum Non Demolition (QND) qubit detection.Comment: references added, slight change
A Feature-Based Comparison of Evolutionary Computing Techniques for Constrained Continuous Optimisation
Evolutionary algorithms have been frequently applied to constrained
continuous optimisation problems. We carry out feature based comparisons of
different types of evolutionary algorithms such as evolution strategies,
differential evolution and particle swarm optimisation for constrained
continuous optimisation. In our study, we examine how sets of constraints
influence the difficulty of obtaining close to optimal solutions. Using a
multi-objective approach, we evolve constrained continuous problems having a
set of linear and/or quadratic constraints where the different evolutionary
approaches show a significant difference in performance. Afterwards, we discuss
the features of the constraints that exhibit a difference in performance of the
different evolutionary approaches under consideration.Comment: 16 Pagesm 2 Figure
Charakterisierung der Leistungsfähigkeit von PEM-Wasser-Elektrolysezellen, die mit und ohne Strömungskanäle arbeiten, basierend auf experimentell validierten semi-empirischen gekoppelten physikalischen Modellen
PEM water electrolysis is a clean technology for hydrogen production. In spite of its many advantages, the costs of the conventional PEM electrolysis cell makes it commercially less competitive vis-à-vis its peers. An alternative cell design has been proposed which has up to a 25 % costs advantage over the conventional cell. In this alternative cell design, the flow channel plate which bears the most costs in the conventional cell design has been replaced with a 3-D Porous Transport Layer (PTL) structure. It has however, been observed that the conventional cell by far out performs the low cost cell at high current density operations, due to increased mass transport limitation in the later. Industrial and commercial hydrogen production efforts are focused towards high current density operation (> 3 A/cm²), so the alternative cell design must be optimized for mass transport limitation.
PEM water electrolysis is a clean technology for hydrogen production. In spite of its many advantages, the costs of the conventional PEM electrolysis cell makes it commercially less competitive vis-à-vis its peers. An alternative cell design has been proposed which has up to a 25 % costs advantage over the conventional cell. In this alternative cell design, the flow channel plate which bears the most costs in the conventional cell design has been replaced with a 3-D Porous Transport Layer (PTL) structure. It has however, been observed that the conventional cell by far out performs the low cost cell at high current density operations, due to increased mass transport limitation in the later. Industrial and commercial hydrogen production efforts are focused towards high current density operation (> 3 A/cm²), so the alternative cell design must be optimized for mass transport limitation.
This work seeks to understand the source of, and to eliminate the mass transport losses in the alternative cell design to get it performing at least as good as the conventional cell at current densities up to 5 A/cm². A 2-D non-isothermal semi-empirical fully-coupled models of both cell designs have been developed and experimentally validated. The developed validated models were then used as tools to simulate and predict the best operating conditions, design parameters and micro-structural properties of the PTL at which the mass transport issues in the alternate cell will be at its minimum, at high current densities. The models are based on a multi-physics approach in which thermodynamic, electrochemical, thermal and mass transport sub-models are coupled and solved numerically, to predict the cell polarization and individual overpotentials, as well as address heat and water management issues. The most unique aspect of this work however, is the development of own semi-empirical equations for predicting the mass transport overpotential imposed by the gas phase (bubbles) at high current densities. For the very first time, calculated polarization curves up to 5 A/cm² have been validated by own experimental data. The results show that, the temperature and pressure, water flowrate and thickness of the PTL are the critical parameters for mitigating mass transport limitation. It was found that, for the size of the cells studied (25 cm² active area each), when both cells are operating at the same temperature of 60 °C, alternative design will have a comparable performance to the conventional designed cell even at 5 A/cm² current density when; the operating pressure is ≥ 5 bar, the feed water flowrate is ≥ 0.024l/min∙cm², PTL porosity is 50 %, PTL pore size is ≥ 11 µm and PTL thickness is 0.5 mm. At these operating, design and micro-structural conditions, the predicted difference between the polarizations of both cells will be only ~10 mV at 5 A/cm² operating current density.Die PEM Wasser Elektrolyse gilt als effiziente Technologie zur Herstellung von sauberem Wasserstoff zur Energiespeicherung. Trotz der vielen Vorteile führen hohe Kosten für die Produktion konventioneller Komponenten und Stacks zu einer nicht konkurrenzfähigen Technologie. Ein alternatives und kostengünstiges Zelldesign wurde vorgestellt, das, verglichen mit einem konventionellen Design, einen Kostenvorteil von bis zu 25 % hervorbringt. Bei diesem alternativen Zelldesign wird die Platte mit Strömungskanälen, die den größten Kostenanteil birgt, durch eine 3-D poröse Struktur (PTL) ersetzt. Bei hohen Stromdichten zeigt aber ein Design ohne Strömungskanäle niedrigere Leistungsdaten, was durch eine gesteigerte Limitierung des Massentransportes erklärt werden kann. Da sich die industrielle und kommerzielle Wasserstoffproduktion in Richtung hoher Stromdichten (> 3 A/cm²) entwickelt, scheint das erforderliche Verständnis von Massentransporteffekten offensichtlich das kosteneffiziente Design gegenüber dem konventionellen Design voran zu treiben. Diese Arbeit versucht den Ursprung von Massentransportlimitierung des kostengünstigen Zelldesigns zu verstehen und zu eliminieren. Um diese Zielvorgabe zu erreichen, wurden 2-D nicht-isotherme, semi-empirische, vollständig gekoppelte Modelle beider Zelldesigns entwickelt und experimentell validiert. Die entwickelten und validierten Modelle wurden als Werkzeug zur Simulation und Vorhersage der am besten geeigneten Betriebs- und Designparameter, sowie Eigenschaften der Mikrostrukur der PTL verwendet. Die hierin entwickelten Modelle basieren auf einem multiphysikalischen Ansatz, worin thermodynamische, elektrische und thermische Effekte sowie Massentransportuntermodelle gekoppelt und gelöst wurden, um sowohl die Zellpolarisation und individuelle Überpotentiale vorherzusagen, als auch Wärme- und Wassermanagement zu adressieren. Das Alleinstellungsmerkmal dieser Arbeit ist jedoch die Entwicklung von semi-empirischen Gleichungen, um die Überpotentiale der Massentransporthemmung, ausgehend von Gasblasen, vorhersagen zu können. Ebenso wurden zum ersten Mal berechnete PEM Wasser Elektrolyse Polarisationskurven bis zu einer Stromdichte von 5 A/cm² mit eigenen Daten validiert. Die Ergebnisse zeigen, dass Temperatur und Druck, sowie Wasserflußrate und Dicke der PTL die kritischen Parameter sind, um Massentransportlimitierung zu vermeiden. Es wurde sogar gezeigt, dass bei der verwendeten Zellgröße (aktive Fläche = 25 cm²) vergleichbare Leistungsdaten bei 60 °C und 5 A/cm² erreicht werden können, sofern der Betriebsdruck 5 bar übersteigt, die Wasserflussrate größer als 0.024 l/min ist, die Porosität der PTL 50 % übersteigt, die Porendurchmesser größer als 11 µm sind und die PTL Dicke bei 0.5 mm liegt. Bei diesen Parametern wurden Unterschiede zwischen den beiden Zelldesigns von etwa 10 mV bei 5 A/cm² vorhergesagt
A directed mutation operator for real coded genetic algorithms
Copyright @ Springer-Verlag Berlin Heidelberg 2010.Developing directed mutation methods has been an interesting research topic to improve the performance of genetic algorithms (GAs) for function optimization. This paper introduces a directed mutation (DM) operator for GAs to explore promising areas in the search space. In this DM method, the statistics information regarding the fitness and distribution of individuals over intervals of each dimension is calculated according to the current population and is used to guide the mutation of an individual toward the neighboring interval that has the best statistics result in each dimension. Experiments are carried out to compare the proposed DM technique with an existing directed variation on a set of benchmark test problems. The experimental results show that the proposed DM operator achieves a better performance than the directed variation on most test problems
Electronic structure and total energy of interstitial hydrogen in iron: Tight binding models
An application of the tight binding approximation is presented for the
description of electronic structure and interatomic force in magnetic iron,
both pure and containing hydrogen impurities. We assess the simple canonical
d-band description in comparison to a non orthogonal model including s and d
bands. The transferability of our models is tested against known properties
including the segregation energies of hydrogen to vacancies and to surfaces of
iron. In many cases agreement is remarkably good, opening up the way to quantum
mechanical atomistic simulation of the effects of hydrogen on mechanical
properties
Chaos-assisted emission from asymmetric resonant cavity microlasers
We study emission from quasi-one-dimensional modes of an asymmetric resonant
cavity that are associated with a stable periodic ray orbit confined inside the
cavity by total internal reflection. It is numerically demonstrated that such
modes exhibit directional emission, which is explained by chaos-assisted
emission induced by dynamical tunneling. Fabricating semiconductor microlasers
with the asymmetric resonant cavity, we experimentally demonstrate the
selective excitation of the quasi-one-dimensional modes by employing the device
structure to preferentially inject currents to these modes and observe
directional emission in good accordance with the theoretical prediction based
on chaos-assisted emission.Comment: 9 pages, 10 figures, some figures are in reduced qualit
Experimental Comparisons of Derivative Free Optimization Algorithms
In this paper, the performances of the quasi-Newton BFGS algorithm, the
NEWUOA derivative free optimizer, the Covariance Matrix Adaptation Evolution
Strategy (CMA-ES), the Differential Evolution (DE) algorithm and Particle Swarm
Optimizers (PSO) are compared experimentally on benchmark functions reflecting
important challenges encountered in real-world optimization problems.
Dependence of the performances in the conditioning of the problem and
rotational invariance of the algorithms are in particular investigated.Comment: 8th International Symposium on Experimental Algorithms, Dortmund :
Germany (2009
Self-consistent multi-mode lasing theory for complex or random lasing media
A semiclassical theory of single and multi-mode lasing is derived for open
complex or random media using a self-consistent linear response formulation.
Unlike standard approaches which use closed cavity solutions to describe the
lasing modes, we introduce an appropriate discrete basis of functions which
describe also the intensity and angular emission pattern outside the cavity.
This constant flux (CF) basis is dictated by the Green function which arises
when formulating the steady state Maxwell-Bloch equations as a self-consistent
linear response problem. This basis is similar to the quasi-bound state basis
which is familiar in resonator theory and it obeys biorthogonality relations
with a set of dual functions. Within a single-pole approximation for the Green
function the lasing modes are proportional to these CF states and their
intensities and lasing frequencies are determined by a set of non-linear
equations. When a near threshold approximation is made to these equations a
generalized version of the Haken-Sauermann equations for multi-mode lasing is
obtained, appropriate for open cavities. Illustrative results from these
equations are given for single and few mode lasing states, for the case of
dielectric cavity lasers. The standard near threshold approximation is found to
be unreliable. Applications to wave-chaotic cavities and random lasers are
discussed.Comment: 18 pages, 9 figure
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